Direct Answer
The main difference between Ca31Si60 and Ca28Si60 is calcium activity and process intensity.
Ca31Si60 contains more calcium and is generally used when stronger inclusion modification, deeper desulfurization, and higher steel cleanliness are required.
Ca28Si60 is more balanced and easier to control, making it a practical choice for routine steelmaking, stable refining, and cost-sensitive production.
Why Do Steel Plants Compare Ca31Si60 and Ca28Si60?
In steelmaking, calcium silicon is not selected by composition alone. The real question is how a grade behaves in molten steel and whether it fits the refining target.
Steel plants usually compare Ca31Si60 and Ca28Si60 when they need to decide between:
- stronger metallurgical effect
- more stable process control
- higher cleanliness requirement
- better cost-performance balance
This is why the difference between the two grades matters in actual production.
What Is Ca31Si60?
Ca31Si60 is a higher-calcium silicon alloy typically used in secondary refining processes where calcium treatment plays a more important role.
Its higher calcium content gives it stronger ability in:
- sulfur removal
- inclusion modification
- improving nozzle flow behavior
- supporting clean steel production
Because of this, Ca31Si60 is more often used in demanding steel grades and cleaner casting conditions.
What Is Ca28Si60?
Ca28Si60 is a medium-calcium silicon alloy widely used in steelmaking as a deoxidizer and inclusion control material.
Compared with Ca31Si60, it offers:
- more stable reaction behavior
- easier process control
- lower treatment intensity
- wider suitability in routine steel production
It is commonly chosen when the plant needs reliable refining performance without overly aggressive calcium activity.
How Does Calcium Content Change Performance?
The increase from Ca28 to Ca31 may look small on paper, but in steelmaking it changes reaction behavior in a meaningful way.
Higher calcium content usually means:
- stronger reactivity in molten steel
- more active sulfur capture
- more effective inclusion transformation
- greater sensitivity to timing and process window
That is why Ca31Si60 can produce stronger metallurgical results, but it also requires better control.
Ca28Si60, by contrast, is often easier to use under stable and repetitive operating conditions.
Which Grade Is Better for Deoxidation?
Both grades can contribute to deoxidation, mainly through their silicon content.
However, in practical steelmaking:
- Ca28Si60 is usually preferred for controlled and stable deoxidation
- Ca31Si60 is used when deoxidation is combined with stronger calcium treatment goals
If the main target is basic oxygen control with balanced refining, Ca28Si60 is often sufficient.
If the plant is also focusing on inclusion shape control and cleaner steel, Ca31Si60 may be more suitable.
Which Grade Is Better for Desulfurization?
Ca31Si60 is generally better for desulfurization because its higher calcium content increases sulfur reaction potential.
This makes it more effective in processes where:
- sulfur targets are tighter
- cleaner steel is required
- downstream quality is more sensitive to sulfur content
Ca28Si60 can still provide desulfurization, but its effect is usually more moderate and better suited to standard steel grades rather than deep sulfur control.
Which Grade Is Better for Inclusion Modification?
This is where the difference becomes more important.
Ca31Si60 is usually more effective for inclusion modification, especially in aluminum-killed steel. It is better at converting solid alumina inclusions into liquid or low-melting calcium aluminates.
That helps reduce:
- nozzle clogging
- casting instability
- harmful solid inclusions
- surface defects in final steel
Ca28Si60 can also improve inclusion behavior, but its modification effect is generally milder and more suitable for applications where extreme cleanliness is not required.
How Do They Perform in Continuous Casting?
For continuous casting, both grades can be used, but the selection depends on process target.
Ca31Si60 is usually preferred when the plant is dealing with:
- nozzle clogging
- high cleanliness requirements
- more severe inclusion-related casting problems
Ca28Si60 is often selected when the goal is:
- stable casting behavior
- cost-effective refining
- controlled routine production
In other words, Ca31Si60 is usually the stronger solution, while Ca28Si60 is often the more economical and stable one.
Which Grade Is Better for Clean Steel?
For clean steel production, Ca31Si60 is generally the better choice.
Clean steel requires stricter control of:
- oxygen
- sulfur
- non-metallic inclusions
- casting cleanliness
Because Ca31Si60 provides stronger calcium treatment, it is more suitable for:
- bearing steel
- automotive steel
- pipeline steel
- other high-grade steels
Ca28Si60 can still be used in cleaner production lines, but it is more commonly associated with standard refining rather than high-cleanliness targets.
Which Grade Is Easier to Control in Production?
Ca28Si60 is usually easier to control.
That is one of its practical advantages. In many steel plants, especially those with continuous and repetitive production, stability matters as much as metallurgical strength.
Ca28Si60 offers:
- more predictable reaction
- easier addition control
- less risk of excessive calcium activity
- smoother integration into routine refining practice
Ca31Si60 can give stronger results, but it is also more sensitive to:
- steel temperature
- oxygen level
- addition timing
- feeding method
So if plant conditions are not tightly controlled, the stronger grade may not always produce proportionally better results.
Which Grade Is More Cost-Effective?
That depends on how cost is measured.
If cost is judged only by purchase price, Ca28Si60 is usually the more economical option.
If cost is judged by refining result, casting stability, and steel cleanliness, Ca31Si60 may create better value in high-end applications.
A practical way to think about it is:
- Ca28Si60 = better for stable routine production and cost control
- Ca31Si60 = better for higher metallurgical performance and cleaner steel
So the cheaper grade is not always the lower-cost choice in total production terms.
When Should You Choose Ca28Si60?
Ca28Si60 is usually a better choice when:
- steel grades are standard or mid-range
- process stability is more important than maximum calcium activity
- cost control is a major factor
- the refining line runs on repeatable routine production
- moderate inclusion control is sufficient
It is a practical grade for many steel plants that need dependable refining without aggressive treatment.
When Should You Choose Ca31Si60?
Ca31Si60 is usually a better choice when:
- cleaner steel is required
- inclusion modification is critical
- nozzle clogging is a recurring problem
- sulfur targets are tighter
the plant produces high-grade or continuous casting steel with strict quality requirements
It is more suitable for operations where refining quality directly affects final product value.
A Practical Comparison Table
| Item | Ca28Si60 | Ca31Si60 |
|---|---|---|
| Calcium activity | Moderate | Higher |
| Deoxidation control | More stable | Stronger but more sensitive |
| Desulfurization | Moderate | Stronger |
| Inclusion modification | Good | Better |
| Clean steel suitability | Standard to medium | High |
| Casting support | Stable routine casting | Better for clogging control |
| Process control difficulty | Easier | Higher |
| Cost level | Lower | Higher |
Conclusion
The difference between Ca31Si60 and Ca28Si60 is not just three points of calcium. It is a difference in refining intensity, process control, and target steel quality.
Ca28Si60 is generally better for stable steelmaking, routine refining, and cost-effective production.
Ca31Si60 is better for clean steel, stronger inclusion modification, and applications where higher metallurgical performance is required.
The best choice depends on what your steelmaking process needs most: stability and economy, or stronger refining effect and cleaner steel.
Looking for the Right CaSi Grade?
If you are selecting between Ca28Si60 and Ca31Si60 for steelmaking or continuous casting, the right grade should match your sulfur target, inclusion control requirement, and production conditions.
Contact us for technical recommendations, specifications, and the latest quotation for different calcium silicon grades.
FAQ
Q:What is the main difference between Ca31Si60 and Ca28Si60?
A:The main difference lies in calcium content and reaction intensity. Ca31Si60 has higher calcium and provides stronger inclusion modification and desulfurization, while Ca28Si60 offers more stable and controlled performance for routine steelmaking.
Q:Which grade is better for clean steel production?
A:Ca31Si60 is generally preferred for clean steel because it provides stronger calcium treatment, improves inclusion modification, and helps reduce nozzle clogging in continuous casting.
Q:Is Ca28Si60 enough for standard steelmaking?
A:Yes, Ca28Si60 is widely used in standard and low-alloy steel production due to its stable reaction behavior and cost-effectiveness.
Q:Does higher calcium content always mean better performance?
A:Not always. Higher calcium increases reaction intensity, but it also requires better process control. In some cases, Ca28Si60 may perform more consistently in stable production conditions.
Q:How do I choose between Ca31Si60 and Ca28Si60?
A:Choose Ca28Si60 for stable, cost-controlled production, and Ca31Si60 for higher cleanliness requirements, stronger inclusion control, and improved casting performance.




